Darstellung und Umlagerungen von 7, 7??Bis (dialkylaluminio)??1??heptenen

R Rienäcker, D Schwengers

Index: Rienaecker,R.; Schwengers,D. Justus Liebigs Annalen der Chemie, 1977 , p. 1633 - 1641

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Citation Number: 4

Abstract

Abstract Dialkylaluminiumhydride 2 und 1-Hepten-6-in (10) oder 3-Methyl-1-hepten-6-in (23) reagieren sowohl in Diethylether als auch ohne Lösungsmittel zu 7, 7-Bis (dialkylaluminio)-1-hepten 12 bzw. zu 7, 7-Bis (dialkylaluminio)-3-methyl-1-hepten 25. Während die Etheraddukte von 12 und 25 isoliert werden können, unterliegen die donatorfreien Verbindungen bereits um 0 C Umwandlungen zu [Bis (dialkylaluminio) ...

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