Supramolecular Side-Chain Functionalized Polymers: Synthesis and Self-Assembly Behavior of Polynorbornenes Bearing PdII SCS Pincer Complexes
JM Pollino, M Weck
Index: Pollino, Joel M.; Weck, Marcus Synthesis, 2002 , # 9 p. 1277 - 1285
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Citation Number: 42
Abstract
Abstract A new polynorbornene bearing palladated SCS pincer complexes at each repeat unit has been synthesized using ring-opening metathesis polymerization. Small mesogenic molecules possessing nitrile or pyridine-based anchoring units are instantaneously and quantitatively coordinated to the palladium center in one simple self-assembly step giving rise to a densely functionalized polymer. These results suggest that the coordination of ...
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