Peroxide route to pentaoxyphosphoranes

DB Denney, DH Jones

Index: Denney,D.B.; Jones,D.H. Journal of the American Chemical Society, 1969 , vol. 91, p. 5821 - 5825

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Citation Number: 37

Abstract

Abstract: A variety of pentaoxyphosphoranes have been prepared by allowing trisubstituted phosphites to react with diethyl peroxide. In one case the same pentaoxyphosphorane was prepared by condensation of p-naphthoquinone and triethyl phoshite and by reaction of the phosphite, 3, with diethyl peroxide. The relative rates of formation of the pentaoxyphosphoranes have been obtained as a function of structure. Decomposition of ...