Organic letters

Ru-catalyzed hydroamidation of alkenes and cooperative aminocarboxylation procedure with chelating formamide

S Ko, H Han, S Chang

Index: Ko, Sangwon; Han, Hoon; Chang, Sukbok Organic Letters, 2003 , vol. 5, # 15 p. 2687 - 2690

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Citation Number: 68

Abstract

A strategy of chelation-assisted activation of formamide was employed to achieve hydroamidation of alkenes to generate one-carbon-elongated amides in moderate to good selectivity and yields. Also reported is the two-metal-catalyzed cooperative aminocarboxylation of aryl iodides, in which Ru is presumed to catalyze decarbonylation of formamide to release carbon monoxide and amine for the subsequent Pd-catalyzed ...

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