Synlett

A Convenient Preparation of 4-Carboxamide Derivatives of Pyridazino [4, 5-b] indoles and Pyridazino [4, 5-b] benzo [b] furans

JC González-Gómez, E Uriarte

Index: Gonzalez-Gomez, Jose C.; Uriarte, Eugenio Synlett, 2002 , # 12 p. 2095 - 2097

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Citation Number: 4

Abstract

Abstract Diels-Alder reaction of indole or 3-coumaranone with 3, 6-dicarbomethoxy-1, 2, 4, 5- tetrazine followed by MgCl 2-mediated C-4 regioselective amidation of the tricyclic diester and subsequent Krapcho dealkoxycarbonylation, provided a convenient route to 4- carboxamide derivatives of pyridazino [4, 5-b] indoles and pyridazino [4, 5-b] benzo [b] furans. 1, 4-Biscarboxamide derivatives were also obtained by full amidation of diester ...

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