Selective vicarious nucleophilic amination of 3-nitropyridines
JM Bakke, H Svensen, R Trevisan
Index: Bakke, Jan M.; Svensen, Harald; Trevisan, Raffaela Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 4 p. 376 - 378
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Citation Number: 29
Abstract
Nine 3-nitropyridine compounds and 4-nitroisoquinoline have been aminated in the 6- position (for 4-nitroisoquinoline in the 1-position) by vicarious nucleophilic substitution reactions. Two amination reagents were used, hydroxylamine and 4-amino-1, 2, 4-triazole. The yields were from moderate to good. Use of hydroxylamine gave an easy work-up procedure by which almost pure product was obtained directly, but 4-amino-1, 2, 4-triazole ...
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