Optimising the synthesis, polymer membrane encapsulation and photoreduction performance of Ru (II)-and Ir (III)-bis (terpyridine) cytochrome c bioconjugates

…, DC Goldstein, M Bhadbhade, P Thordarson

Index: Hvasanov, David; Mason, Alexander F.; Goldstein, Daniel C.; Bhadbhade, Mohan; Thordarson, Pall Organic and Biomolecular Chemistry, 2013 , vol. 11, # 28 p. 4602 - 4612

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Citation Number: 17

Abstract

Ruthenium (II) and iridium (III) bis (terpyridine) complexes were prepared with maleimide functionalities in order to site-specifically modify yeast iso-1 cytochrome c possessing a single cysteine residue available for modification (CYS102). Single X-ray crystal structures were solved for aniline and maleimide Ru (II) 3 and Ru (II) 4, respectively, providing detailed structural detail of the complexes. Light-activated bioconjugates prepared from Ru (II) 4 in ...

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