Hydrido RuII organometallics; synthesis, spectral and catalytic hydrogenation studies
P MURALIDHAR REDDY, C KRISTA REDDY…
Index: Muralidhar Reddy; Krista Reddy; Shobha Rani; Buchi Reddy; Ravinder Journal of the Indian Chemical Society, 2007 , vol. 84, # 8 p. 733 - 738
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Abstract
Résumé/Abstract The reaction between RuCl 3. 3H 2 O and tertiary phosphines in formaldehyde results in the formation of hydrido organometallics of the type [RuH (Cl)(CO) L 3]. From these another series of hydrido organometallics were derived by replacing one of the tertiary phosphines with pyrazole moiety and isolated the compounds of type [RuH (Cl)(CO) L 2 Pz], where L=(2-formylphenyl) diphenylphosphine,(3-carboxyphcnyl) ...
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