Bond localization approach to the carbon analog of the Claisen rearrangement. Thermolysis of 4-aryl-1-butenes
JB Lambert, DM Fabricius, JA Hoard
Index: Lambert,J.B. et al. Journal of Organic Chemistry, 1979 , vol. 44, # 9 p. 1480 - 1485
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Citation Number: 18
Abstract
Results 4-Phenyl-1-butene was obtained from commercial sources. The naphthyl (2) and phenanthryl (3) substrates were obtained by Grignard coupling reactions. Both were initially prepared, isolated, and characterized as products of the coupling between the appropriate arylmagnesium bromide and 4-bromo-1-butene. Improved yields and easier purification, however, were obtained by coupling of the appropriate arylhalomethane with ...
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