Efficient Epoxidation of Electron??Deficient Alkenes with Hydrogen Peroxide Catalyzed by [γ??PW10O38V2 (μ??OH) 2] 3−
…, K Sugahara, K Yonehara, R Ishimoto…
Index: Kamata, Keigo; Sugahara, Kosei; Yonehara, Kazuhiro; Ishimoto, Ryo; Mizuno, Noritaka Chemistry - A European Journal, 2011 , vol. 17, # 27 p. 7549 - 7559
Full Text: HTML
Citation Number: 39
Abstract
Abstract A divanadium-substituted phosphotungstate,[γ-PW 10 O 38 V 2 (μ-OH) 2] 3−(I), showed the highest catalytic activity for the H 2 O 2-based epoxidation of allyl acetate among vanadium and tungsten complexes with a turnover number of 210. In the presence of I, various kinds of electron-deficient alkenes with acetate, ether, carbonyl, and chloro groups at the allylic positions could chemoselectively be oxidized to the corresponding epoxides ...
Related Articles:
[Mizuno, Noritaka; Kamata, Keigo; Yamaguchi, Kazuya Catalysis Today, 2012 , vol. 185, # 1 p. 157 - 161]
Oxidation of alkenes and sulfides catalyzed by a new binuclear molybdenum bis-oxazoline complex
[Moshref Javadi, Maedeh; Moghadam, Majid; Mohammadpoor-Baltork, Iraj; Tangestaninejad, Shahram; Mirkhani, Valiollah; Kargar, Hadi; Tahir, Muhammad Nawaz Polyhedron, 2014 , vol. 72, p. 19 - 26]
[Cantonetti, Veronica; Monti, Donato; Venanzi, Mariano; Bombelli, Cecilia; Ceccacci, Francesca; Mancini, Giovanna Tetrahedron Asymmetry, 2004 , vol. 15, # 13 p. 1969 - 1977]
[De Villa P., Aida L.; Sels, Bert F.; De Vos, Dirk E.; Jacobs, Pierre A. Journal of Organic Chemistry, 1999 , vol. 64, # 19 p. 7267 - 7270]
[Battioni, P.; Renaud, J. P..; Bartoli, J. F.; Reina-Artiles, M.; Fort, M.; Mansuy, D. Journal of the American Chemical Society, 1988 , vol. 110, # 25 p. 8462 - 8470]