Journal of the American Chemical Society

Highly selective 1, 3-isomerization of allylic alcohols via rhenium oxo catalysis

C Morrill, RH Grubbs

Index: Morrill, Christie; Grubbs, Robert H. Journal of the American Chemical Society, 2005 , vol. 127, # 9 p. 2842 - 2843

Full Text: HTML

Citation Number: 85

Abstract

Two reaction strategies are developed to promote the highly selective 1, 3-isomerization of a variety of allylic alcohols using O3ReOSiPh3 as a catalyst. The first strategy utilizes substrates whose 1, 3-regioisomer contains a conjugated alkene, which relies on thermodynamics to obtain high selectivity. The second strategy employs N, O-bis (trimethylsilyl) acetamide as an additive to selectively and irreversibly remove the product ...

Related Articles:

The reaction of acetal-type protective groups in combination with TMSOTf and 2, 2′-bipyridyl; mild and chemoselective deprotection and direct conversion to other …

[Fujioka, Hiromichi; Minamitsuji, Yutaka; Kubo, Ozora; Senami, Kento; Maegawa, Tomohiro Tetrahedron, 2011 , vol. 67, # 16 p. 2949 - 2960]

Reduction of Aromatic and Aliphatic Esters Using the Reducing Systems MoO2 (acac) 2 or V (O)(OiPr) 3 in Combination with 1, 1, 3, 3??Tetramethyldisiloxane

[Pehlivan, Leyla; Metay, Estelle; Laval, Stephane; Dayoub, Wissam; Delbrayelle, Dominique; Mignani, Gerard; Lemaire, Marc European Journal of Organic Chemistry, 2011 , # 36 p. 7400 - 7406]

Conjugate reduction of 2-butene-1, 4-diones with LiAlH4-SbCl3.

[Bulletin of the Chemical Society of Japan, , vol. 64, # 1 p. 306 - 308]

A novel, chemoselective and efficient microwave-assisted deprotection of silyl ethers with selectfluor

[Saxena, Ira; Deka, Nabajyoti; Sarma, Jadab C.; Tsuboi, Sadao Synthetic Communications, 2003 , vol. 33, # 23 p. 4005 - 4011]

A novel, chemoselective and efficient microwave-assisted deprotection of silyl ethers with selectfluor

[Saxena, Ira; Deka, Nabajyoti; Sarma, Jadab C.; Tsuboi, Sadao Synthetic Communications, 2003 , vol. 33, # 23 p. 4005 - 4011]

More Articles...