Total synthesis of amphimedine

AM Echavarren, JK Stille

Index: Echavarren, Antonio M.; Stille, J. K. Journal of the American Chemical Society, 1988 ,  vol. 110,  # 12  p. 4051 - 4052

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Citation Number: 52

Abstract

1 2 krcl krel krei alkene 106P(direct)* 1 06kb(direct) g(compet) h maleic anhydridec 1200 20 570 57 90 fumaronitriIed 3 20 5.1 11 1.1 1.5 dimethyl fumarate ' 63 1. o 10 1. o 1. o acrylonitrild 0.42 0.0067 0.024 0.0024 0.0083 “In CH $ N solvent. MI sI. cConcentration range 0-0.011 M. d0-0.014 M. e0-0.048 M. f0-2 M.# Determined from absolute rate measurements (present work). Determined from competition experiments (ref 6a).