The synthesis of 3, 4??2H2??3Z??hexenal and 6, 6, 6??2H3??3Z??hexenal

S Fielder, DD Rowan

Index: Fielder; Rowan Journal of Labelled Compounds and Radiopharmaceuticals, 1995 , vol. 36, # 5 p. 465 - 470

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Citation Number: 14

Abstract

Abstract 6, 6, 6-2 H 3-3Z-Hexenal (3b) has been prepared in 89% yield and in greater than 94% purity by the oxidation of 6, 6, 6-2 H 3-3Z-Hexen-1-ol (2b) with the Dess/Martin periodinane (1) in fluorotrichloromethane (freon 11). Use of the freon solvent greatly improved the recovery of this volatile aldehyde. Similarly the oxidation of 3, 4-2 H 2-3Z- hexen-1-ol (5) yielded 3, 4-2 H 2-3Z-hexenal (6) in a 92% isolated yield with a purity of ...

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