Mechanism and structure-reactivity correlation in the homogeneous, unimolecular elimination kinetics of 2-substituted ethyl methylcarbonates in the gas phase
…, E Marquez, A Herize, RM Dominguez…
Index: Chuchani, Gabriel; Marquez, Edgar; Herize, Armando; Dominguez, Rosa Maria; Tosta, Maria; Brusco, Doris Journal of Physical Organic Chemistry, 2003 , vol. 16, # 11 p. 839 - 848
Full Text: HTML
Citation Number: 9
Abstract
ABSTRACT: The gas-phase elimination kinetics of 2-substituted ethyl methylcarbonates were determined in a static reaction system over the temperature range of 323–435 C and pressure range 28.5–242 Torr. The reactions are homogeneous, unimolecular and follow a first-order rate law. The kinetic and thermodynamic parameters are reported. The 2- substituents of the ethyl methylcarbonate (CH3OCOOCH2CH2Z, Z ¼substituent) give an ...
Related Articles:
Synthesis of dialkyl carbonates from CO 2 and alcohols via electrogenerated N-heterocyclic carbenes
[Wu, La-Xia; Wang, Huan; Xiao, Yan; Tu, Zhuo-Ying; Ding, Bin-Bin; Lu, Jia-Xing Electrochemistry Communications, 2012 , vol. 25, # 1 p. 116 - 118]
Easy eco-friendly phenonium ion production from phenethyl alcohols in dimethyl carbonate
[Barontini; Proietti Silvestri; Nardi; Bovicelli; Pari; Gallucci; Spezia; Righi Tetrahedron Letters, 2013 , vol. 54, # 37 p. 5004 - 5006]