1: 2??sequence??regulated radical copolymerization of naturally occurring terpenes with maleimide derivatives in fluorinated alcohol
…, K Satoh, M Kamigaito
Index: Matsuda, Masaru; Satoh, Kotaro; Kamigaito, Masami Journal of Polymer Science, Part A: Polymer Chemistry, 2013 , vol. 51, # 8 p. 1774 - 1785
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Citation Number: 27
Abstract
Abstract Naturally occurring bulky terpenes, such as (+)-and (–)-limonene and (–)-β-pinene, were quantitatively copolymerized with maleimide (MI) derivatives (ie, phenyl-, cyclohexyl-, ethyl-, and unsubstituted-MI) in PhC (CF 3) 2 OH solvent via selective 1: 2-alternating propagation governed by the penultimate effect, which resulted in 1: 2-sequence regulated polymers with relatively high glass transition temperatures and optical activities. Similar ...
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