Homolytic Chlorination of Aliphatic Compounds. III. Photochlorination of 1-Substituted Propanes; Steric Effects

M Kosugi, K Takeuchi, T Migita

Index: Kosugi,M. et al. Bulletin of the Chemical Society of Japan, 1969 , vol. 42, p. 3354 - 3357

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Citation Number: 9

Abstract

We have recently discussed the relative reactivities of aliphatic compounds in liquid-phase photochlorination and found that in CH3-X type compounds inductive effect of the substituents X was the" principal factor controlling the reactivities. 1-3) A linear free energy relationship was found between the reactivities of methyl hydrogens and