The Journal of Organic Chemistry

1, 2-bis (2-hydroxyethyl) hydrazine and derivatives

AT Nielsen, GW Lawrence

Index: Nielsen,A.T.; Lawrence,G.W. Journal of Organic Chemistry, 1977 , vol. 42, p. 2900 - 2902

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Citation Number: 5

Abstract

Glycolaldehyde was condensed with 2-hydroxyethylhydrazine to yield hydrazone 2 which has been hydrogenated (Pd/C catalyst) to produce the title compound (3). The tetraacetyl and N, N'-diacetyl derivatives of 3 (7 and 8, respectively) and the oxidation product, bis (2- hydroxyethy1) diazene (6), are described. The nuclear magnetic resonance spectra of the new compounds, including rotamers of 8, are discussed.