Versatile New C 3-Symmetric Tripodal Tetraphosphine Ligands; Structural Flexibility to Stabilize CuI and RhI Species and Tune Their Reactivity

J Wassenaar, MA Siegler, AL Spek, B de Bruin…

Index: Katritzky, Alan R.; Akutagawa, Kunihiko; Jones, R Alan Synthetic Communications, 1988 , vol. 18, # 10 p. 1151 - 1158

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Citation Number: 17

Abstract

... Volume: Page: ... ligand 3 bears a bridgehead phosphorus atom that is connected at the 2-position of 3-methylindole, thus reversing the overall pattern and synthetic methodology (Scheme 1 ... a Conditions: (i) n-BuLi, THF, −78 °C; CO 2 ; t-BuLi; ClPR 2 (R = Ph, i Pr). ...