The preparation of various aliphatic halides and halohydrin compounds

MT Bogert, EM Slocum

Index: Bogert; Slocum Journal of the American Chemical Society, 1924 , vol. 46, p. 765

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Citation Number: 7

Abstract

For the conversion of trimethylene glycol into the corresponding bromide or iodide, it was ascertained that the phosphorus trihalide could be substituted successfully for the pentahalide. Differences were observed in the behavior of trimethylene glycol with the hydrogen halides. At 0 O, both hydrogen iodide and hydrogen bromide formed solid crystalline addition products with it, which when heated changed nearly quantitatively into ...