Organometallics

R-Allyl Nickel (II) Complexes with Chelating N-Heterocyclic Carbenes: Synthesis, Structural Characterization, and Catalytic Activity

L Benı́tez Junquera, MC Puerta, P Valerga

Index: Benitez Junquera, Lourdes; Puerta, M. Carmen; Valerga, Pedro Organometallics, 2012 , vol. 31, # 6 p. 2175 - 2183

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Citation Number: 22

Abstract

The N-heterocyclic carbene (NHC) nickel complexes [(L) Ni (NHC)][BArF4](ArF= 3, 5-bis (trifluoromethyl) phenyl; L= allyl (1), methylallyl (2); NHC= 1-(2-picolyl)-3-methylimidazol-2- ylidene (a), 1-(2-picolyl)-3-isopropylimidazol-2-ylidene (b), 1-(2-picolyl)-3-n-butylimidazol-2- ylidene (c), 1-(2-picolyl)-3-phenylimidazol-2-ylidene (d), 1-(2-picolyl)-3- methylbenzoimidazol-2-ylidene (e), 1-(2-picolyl)-4, 5-dichloro-3-methylimidazol-2-ylidene ...

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