On cyclic intermediates in substitution reactions. I. The alkaline hydrolysis of some aliphatic bromoacids
JF Lane, HW Heine
Index: Lane; Heine Journal of the American Chemical Society, 1951 , vol. 73, p. 1348,1350
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Citation Number: 9
Abstract
The rates of aqueous decomposition have been determined for a number of sodium salts of monobromoaliphatic acids in which the position of substitution of the bromine atom ranges from a to y. It has been established that (1) the rates of decomposition, as measured by the release of bromide ion, are of the first order with respect to the ion of the haloacid;(2) the entropies of activation are positive, and, on the average, about 10 eu;(3) the heats of ...
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