Hydride transfer and oxyanion addition equilibria of NAD+ analogs

…, ISH Lee, RMG Roberts, MM Kreevoy

Index: Ostovic, Drazen; Lee, In-Sook Han; Roberts, Roger M. G.; Kreevoy, Maurice M. Journal of Organic Chemistry, 1985 , vol. 50, # 22 p. 4206 - 4211

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Citation Number: 47

Abstract

Quilibrium constants, K, have been determined for the reduction of 10-methylacridinium ion by 15 N-heterocyclic hydride donors: acridine, quinoline, pyridine, and phenanthridine derivatives. The solvent was a mixture of 2-propanol and water in the ratio 4: l by volume. Reduction potentials have been estimated for the corresponding cations in aqueous solution by assuming that the ICs would be the same and accepting-361 mV as the reduction ...