Determination of the rate constant and of product branching ratios in the reaction of CH3O2 with OCl between 233 and 300 K

AS Kukui, TPW Jungkamp…

Index: Kukui, A. S.; Jungkamp, T. P. W.; Schindler, R. N. Berichte der Bunsen-Gesellschaft, 1994 , vol. 98, # 10 p. 1298 - 1302

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Citation Number: 27

Abstract

Abstract The reaction CH 3 O 2+ OCl [RIGHTWARDS ARROW] prod (1) has been investigated in the temperature range 233–300 K using discharge flow mass-spectrometric technique. A rate constant k 1 (300 K)=(2.5±0.3) 10− 12 cm 3 molecule− 1 s− 1 has been obtained observing the pseudo-first-order decay of CH 3 O 2 radicals. The observed temperature dependence is described by