Journal of the American Chemical Society

The Dimer of 2-Cyano-1, 3-butadiene

CS Marvel, NO Brace

Index: Marvel; Brace Journal of the American Chemical Society, 1949 , vol. 71, p. 37,40

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Citation Number: 14

Abstract

Dimerization is a reaction characteristic of 1, 3-butadiene and its derivatives. Thus, it was not surprising to find that 2-cyano-l13-butadiene on standing in an ice-box, even though picric acid was present, gradually changed to a low-melting solid. The closely related 2-chloro-l13- butadiene has been shown to yield two dimers, the first a cyclohexene derivative and the second a cyclooctadiene derivative (II). a Hence we have considered similar possibilities ...

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