Nitrosation in organic chemistry. Nitrosolysis, a novel carbon-carbon bond cleavage effected through nitrosation. Nitrosolysis of ketones

MM Rogic, J Vitrone, MD Swerdloff

Index: Rogic,M.M. et al. Journal of the American Chemical Society, 1975 , vol. 97, p. 3848 - 3850

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Citation Number: 6

Abstract

the exclusive methyl iodide alkylation product of such anionic solutions. The significantly more sluggish reaction of 9-chlorobarbaralane with n-butyllithium in refluxing etherI3 provided 75% of a 1: l mixture of bicyclo [3.2. 2] nonatriene and its 4-n-butyl derivative l 4 after aqueous protonation.