Kinetics and Mechanism of the Pudovik Reaction in the Azomethine Series: II. 1 Hydrolysis and Catalysis in the Reaction of Dialkyl Phosphites with Benzalaniline

…, OA Mostovaya, RA Cherkasov, AN Pudovik

Index: Sobanov; Zolotukhin; Galkin; Mostovaya; Cherkasov; Pudovik Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 871 - 876

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Citation Number: 5

Abstract

Proceeding with research into the mechanism of re- action of dialkyl phosphites with azomethines [1] we found that the reaction have an induction period (335 min) when fast prepared solutions of freshly purified reagents are used, while with time the ap- parent rate constant steadily increases. Assuming that this fact is explained by absorption of atmospheric moisture, we showed that addition of water eliminates the induction period and prevents increase in the ...