Diastereoselektivität der Geruchswahrnehmung von Alkoholen der Iononreihe

KH Schulte??Elte, W Giersch, B Winter…

Index: Schulte-Elte, Karl H.; Giersch, Wolfgang; Winter, Beat; Pamingle, Herve; Ohloff, Guenther Helvetica Chimica Acta, 1985 , vol. 68, p. 1961 - 1985

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Citation Number: 26

Abstract

The characteristic odor of the diastereoisomers 1 and 2 of l-(2, 2, 6-trimethylcyclohexyl)-3- hexanol is configuration dependent, the trans-alcohol 1 bcing identified as the sensorily active component. Structure modifications of model lj2, for example substitution on C (2), C (13), and C (14)(ionon numbering) by CH, groups, introduction of double bonds in the 3-or 4- position, and isosteric substitution of C (7) by an 0-atom, leads to analogues revealing an ...