Rational Design of a Palladium??Catalyzed Csp–Csp Cross??Coupling Reaction Inspired by Kinetic Studies

Y Weng, B Cheng, C He, A Lei

Index: Weng, Yue; Cheng, Ben; He, Chuan; Lei, Aiwen Angewandte Chemie - International Edition, 2012 , vol. 51, # 38 p. 9547 - 9551

Full Text: HTML

Citation Number: 35

Abstract

Owing to the unique chemical and physical properties of diynes, along with their wide applications in pharmaceuticals and materials chemistry, these compounds have attracted the attention of scientists for decades.[1] However, the synthesis of diynes still remains a great challenge. Compared with the intensively developed synthetic methods for biaryl and arylalkynes (Csp2–Csp2 and Csp2–Csp couplings), the methods for Csp–Csp coupling ...

Related Articles:

Investigation of an Efficient Palladium-Catalyzed C (sp)− C (sp) Cross-Coupling Reaction Using Phosphine− Olefin Ligand: Application and Mechanistic Aspects

[Shi, Wei; Luo, Yingdong; Luo, Xiancai; Chao, Lei; Zhang, Heng; Wang, Jian; Lei, Aiwen Journal of the American Chemical Society, 2008 , vol. 130, # 44 p. 14713 - 14720]

An Efficient Copper??Catalyzed Homocoupling of Terminal Alkynes to Give Symmetrical 1, 4??Disubstituted 1, 3??Diynes

[Zhang, Songlin; Liu, Xiaoyan; Wang, Tongqiang Advanced Synthesis and Catalysis, 2011 , vol. 353, # 9 p. 1463 - 1466]

Contingency and serendipity in the reactions of Fischer carbene complexes with conjugated triynes

[Jiang, May Xiao-Wu; Rawat, Manish; Wulff, William D. Journal of the American Chemical Society, 2004 , vol. 126, # 19 p. 5970 - 5971]

Palladium supported on amine-functionalized mesoporous silica: Highly efficient phosphine-free catalyst for alkyne–alkyne cross-coupling reaction

[Li, Hongling; Wang, Lailai; Yang, Min; Qi, Yanxing Catalysis Communications, 2012 , vol. 17, p. 179 - 183]

AgOTf??Catalyzed Electrophilic Cyclization of Triynols with NXS: Rapid Synthesis of Densely Trisubstituted Naphthalenes and Quinolines

[Chen, Zhiyuan; Jia, Xuegong; Ye, Changqing; Qiu, Guanyinsheng; Wu, Jie Chemistry - An Asian Journal, 2014 , vol. 9, # 1 p. 126 - 130]

More Articles...