FREE RADICAL CHAIN ELIMINATION REACTION (E RC 1). CONVERSION OF VICINAL DINITRO COMPOUNDS OR β-NITRO SULFONES TO OLEFINS WITH …
N Ono, H Miyake, R Tamura, I Hamamoto, A Kaji
Index: Ono, Noboru; Miyake, Hideyoshi; Tamura, Rui; Hamamoto, Isami; Kaji, Aritsune Chemistry Letters, 1981 , p. 1139 - 1142
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Citation Number: 15
Abstract
Vicinal dinitro compounds (1) or β-nitro sulfones (2) are converted to olefins in good yields on treatment with tributyltin hydride. This elimination proceeds by way of an electron transfer chain mechanism. The elimination from 1 is nonstereospecific and the elimination from 2 is stereospecific.
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