Silylation de derives gem-polychlores

J Dunogues, E Jousseaume, R Calas

Index: Dunogues,J. et al. Journal of Organometallic Chemistry, 1974 , vol. 71, p. 377 - 392

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Citation Number: 27

Abstract

Abstract In contrast to the already-known routes which require very low temperature conditions (in the region of− 100), the direct partial silylation of gem-polychlorinated compounds occurs at 30–60 with the organochlorosilane/Mg/HMPT system. This type of reaction permits an easy synthesis of α-chlorinated silylated derivatives which lead to the corresponding α-functional silylated compounds: thus, Ph CO SiMe 3 can be easily ...