Ruthenium-catalyzed cytochrome P-450 type oxidation of tertiary amines with alkyl hydroperoxides

S Murahashi, T Naota, K Yonemura

Index: Murahashi, Shun-Ichi; Naota, Takeshi; Yonemura, Koichi Journal of the American Chemical Society, 1988 , vol. 110, # 24 p. 8256 - 8258

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Citation Number: 208

Abstract

The fluorescence spectra of benzanilide compared with those of N-methylbenzanilide, however, reveal an additional complexity in the former. First of all, the half-width of the green fluorescence of benzanilide (onset 400 nm, & 475 nm, MCH at 298 K) proves to be substantially greater than that of N-methylbenzanilide, Av= 4 1 15 cm-'vs 33 16 cm-'. Secondly, the benzanilide fluorescence half-width markedly contracts as the dielectric ...