A simple, effective, new, palladium-catalyzed conversion of enol silanes to enones and enals
RC Larock, TR Hightower, GA Kraus, P Hahn…
Index: Larock, Richard C.; Hightower, Timothy R.; Kraus, George A.; Hahn, Pat; Zheng, Deye Tetrahedron Letters, 1995 , vol. 36, # 14 p. 2423 - 2426
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Citation Number: 153
Abstract
Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Enol silanes derived from aldehydes and ketones are readily converted to the corresponding α,β-unsaturated carbonyl compounds by 10% Pd(OAc) 2 in the presence of one atmosphere of oxygen in DMSO as the solvent. ... Pd(OAc) 2 in DMSO under 1 atm. of O 2 catalyzes ...
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