Does alkyl chain length really matter? Structure–property relationships in thermochemistry of ionic liquids

…, VN Emel'yanenko, RV Ralys, AV Yermalayeu…

Index: Verevkin, Sergey P.; Zaitsau, Dzmitry H.; Emel'Yanenko, Vladimir N.; Ralys, Ricardas V.; Yermalayeu, Andrei V.; Schick, Christoph Thermochimica Acta, 2013 , vol. 562, p. 84 - 95

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Citation Number: 29

Abstract

DSC was used for determination of reaction enthalpies of synthesis of ionic liquids [Cnmim][Cl]. A combination of DSC with quantum chemical calculations presents an indirect way to study thermodynamics of ionic liquids. The indirect procedure for vaporization enthalpy was validated with the direct experimental measurements by using thermogravimetry. First-principles calculations of the enthalpy of formation in the gaseous ...