Inorganic chemistry

Synthesis and Photophysical Properties of Cyclometalated Platinum (II) 1, 2-Benzenedithiolate Complexes and Heterometallic Derivatives Obtained from the Addition …

F Juliá, PG Jones, P González-Herrero

Index: Julia, Fabio; Jones, Peter G.; Gonzalez-Herrero, Pablo Inorganic Chemistry, 2012 , vol. 51, # 9 p. 5037 - 5049

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Citation Number: 17

Abstract

Anionic cyclometalated platinum (II) 1, 2-benzenedithiolate complexes [Pt (C^ N)(bdt)]−[C^ N= 2-phenylpyridine, 1-(4-tert-butylphenyl) isoquinoline] have been synthesized and employed as metalloligands toward [Au (PCy3)]+ units to obtain heterometallic derivatives of the types [Pt (C^ N)(bdt){Au (PCy3)}] and [Pt (C^ N)(bdt){Au (PCy3)} 2]+. The crystal structures of two of the heterometallic complexes reveal the formation of unusually short Pt ...