Radical combination in the ortho position of trityl radical observed in single-electron transfer reactions of trityl anion

…, PY Lin, K Bellos, P Assithianakis, H Stamm

Index: Werry, Juergen; Lin, Pen-Yuan; Bellos, Konstantinos; Assithianakis, Petros; Stamm, Helmut Journal of the Chemical Society, Chemical Communications, 1990 , # 20 p. 1389 - 1390

Full Text: HTML

Citation Number: 4

Abstract

Single-electron transfer reactions between trityl anion and 1 -acyl-2,2-dimethylaziridines provide, among other products, the methallyl amides 7 and the triphenylmethanes 8 carrying an amidoethyl chain attached with the tertiary carbon ortho to the triphenylmethane. ... Trityl radical (Tr = CPh3) Tr' combines with radicals in the para position; only radicals of low steric demand add to the central carbon. 1 Combination in the ortho position has not been ...