Journal of fluorine chemistry

Synthese de nouveaux diepoxides hautement fluores, precurseurs de tensioactifs bolaphiles a espaceur fluore

CB Serrurier, A Cambon

Index: Serrurier, Cecile Bassilana; Cambon, Aime Journal of Fluorine Chemistry, 1998 , vol. 87, # 1 p. 37 - 40

Full Text: HTML

Citation Number: 6

Abstract

In this paper, we describe the synthesis of new highly fluorinated diepoxides from diols of general formula HOCH2 (CF2) nCH2OH which are not often used in organic synthesis because of their strong acidity, resulting in poor reactivity towards polyaddition and polycondensation. These highly fluorinated diépoxides are obtained by condensation of these diols with epichlorohydrin, in basic medium and with the phase transfer catalyst, ...