Palladium-Catalyzed Regio-and Stereoselective Reduction of Allylic Compounds with LiHBEt 3. Application to the Synthesis of Co-enzyme Q 10
…, H Kinoshita, K Inomata, H Kotake, H Takagaki…
Index: Mohri, Mitsunobu; Kinoshita, Hideki; Inomata, Katsuhiko; Kotake, Hiroshi; Takagaki, Hidetsugu; Yamazaki, Keiji Chemistry Letters, 1986 , p. 1177 - 1180
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Citation Number: 45
Abstract
Regio-and stereoselective desulfonylation of allylic sulfones with LiHBEt 3 in the presence of a catalytic amount of [PdCl 2 (dppp)] was successfully applied to the synthesis of co- enzyme Q 10. It was found that this reduction system was applicable to a wide variety of allylic functional groups.
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