[(η-C 5 H 4 R) Fe (CO) 2 X], X= Cl, Br, I, NO 3, CO 2 Me and [(η-C 5 H 4 R) Fe (CO) 3]+, R=(CH 2) n CO 2 Me (n= 0–2), and CO 2 CH 2 CH 2 OH: a new group of CO- …

…, BE Mann, P Sawle, R Aqil, T Perrior, R Motterlini

Index: Scapens, David; Adams, Harry; Johnson, Tony R.; Mann, Brian E.; Sawle, Philip; Aqil, Rehan; Perrior, Trevor; Motterlini, Roberto Dalton Transactions, 2007 , # 43 p. 4962 - 4973

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Citation Number: 28

Abstract

A new group of CO-releasing molecules, CO-RMs, based on cyclopentadienyl iron carbonyls have been identified. X-Ray structures have been determined for [(η- C5H4CO2Me) Fe (CO) 2X], X= Cl, Br, I, NO3, CO2Me,[(η-C5H4CO2Me) Fe (CO) 2] 2,[(η- C5H4CO2CH2CH2OH) Fe (CO) 2] 2 and [(η-C5H4CO2Me) Fe (CO) 3][FeCl4]. Half-lives for CO release, 1H, 13C, and 17OC NMR and IR spectra have been determined along with ...