Preparation of trifluoromethyl-substituted alcohols from allylsilanes and trifluoroacetic anhydride
H Pellissier, S Wilmouth, M Santelli
Index: Pellissier, Helene; Wilmouth, Serge; Santelli, Maurice Tetrahedron Letters, 1996 , vol. 37, # 29 p. 5107 - 5110
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Citation Number: 22
Abstract
The titanium tetrachloride-mediated addition of allyltrimethylsilane or 1, 8-bis (trimethylsilyl)- 2, 6-octadiene and trifluoroacetic anhydride led to trifluoromethyl-diallylcarbinol or (dl)-1- trifluoromethyl-2, 5-divinylcyclopentanol, respectively, in fair yields; this latter was further converted into several 1-trifluoromethyl-2-vinylcyclopentane derivatives.
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