A versatile radical based approach to O-alkylated hydroxylamines and oximes
B Quiclet-Sire, D Woollaston, SZ Zard
Index: Quiclet-Sire, Beatrice; Woollaston, Daniel; Zard, Samir Z. Tetrahedron, 2008 , vol. 64, # 52 p. 11917 - 11924
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Citation Number: 5
Abstract
O-Alkylhydroxylamines, often used for the preparation of bioconjugates, can be readily obtained by radical addition to suitable O-alkenylhydroxylamine derivatives. In the case of N- Boc-O-allylhydroxylamine, the addition is unexpectedly followed by elimination resulting in an overall allylation of the radical species.
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