Conjugated Asymmetric Donor??Substituted 1, 3, 5??Triazines: New Host Materials for Blue Phosphorescent Organic Light??Emitting Diodes

…, GH Xie, HF Shi, T Tsuboi, W Huang

Index: An, Zhong-Fu; Chen, Run-Feng; Yin, Jun; Xie, Guo-Hua; Shi, Hui-Fang; Tsuboi, Taiju; Huang, Wei Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10871 - 10878

Full Text: HTML

Citation Number: 46

Abstract

Abstract Conjugated asymmetric donor-substituted 1, 3, 5-triazines (ADTs) have been synthesized by nucleophilic substitution of organolithium catalyzed by [Pd (PPh 3) 4]. Theoretical and experimental investigations show that ADTs possess high solubility and thermostability, high fluorescent quantum yield (35%), low HOMO (− 6.0 eV) and LUMO (− 2.8 eV), and high triplet energy (ET, 3.0 eV) according to the different substitution pattern ...