Quenching of singlet oxygen by tertiary aliphatic amines. Structural effects on rates and products
E Baciocchi, T Del Giacco, A Lapi
Index: Baciocchi, Enrico; Del Giacco, Tiziana; Lapi, Andrea Helvetica Chimica Acta, 2006 , vol. 89, # 10 p. 2273 - 2280
Full Text: HTML
Citation Number: 8
Abstract
Abstract A kinetic and product study of the reaction of a series of α-methyl-substituted N- methylpiperidines with thermally generated 1 O 2 in MeCN was carried out. It was found that as the number of α-methyl groups (Me in α-position relative to the N-atom) increases, the rate of 1 O 2 quenching (physical plus chemical) slightly decreases. This finding shows that, with respect to the reaction rate, steric effects are much more important than electronic ...
Related Articles:
[Barba, Fructuoso; Recio, Javier; Batanero, Belen Tetrahedron Letters, 2013 , vol. 54, # 14 p. 1835 - 1838]
Cationic carbon to nitrogen rearrangements in the reactions of N-(sulfonyloxy) amines with aldehydes
[Hoffman, Robert V.; Salvador, James M. Journal of Organic Chemistry, 1992 , vol. 57, # 16 p. 4487 - 4490]
Inhibition of human alcohol dehydrogenases by formamides
[Schindler, John F.; Berst, Kristine B.; Plapp, Bryce V. Journal of Medicinal Chemistry, 1998 , vol. 41, # 10 p. 1696 - 1701]