Acylotropic Tautomerism: XXXV. RL-Inversion of Configuration of Dipolar Spyrocyclic and Open-Chain 2-Arylaminotropone Isomers
LP Olekhnovich, ZN Budarina, GS Borodkin…
Index: Olekhnovich; Budarina; Borodkin; Kurbatov; Vaslyaeva; Zhdanov Russian Journal of Organic Chemistry, 2002 , vol. 38, # 5 p. 713 - 722
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Citation Number: 8
Abstract
Abstract RL-Inversion of chiral spirocyclic and open-chain 2-arylaminotropone derivatives with varied heteroatom (O, S, N) has been studied. Kinetic relations holding in the RL- permutation are discussed. Its mechanism includes formation and dissociation of spiro bonds and torsion stereodynamics.
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