Two new iodine-capped carbon rods
K Gao, NS Goroff
Index: Gao, Kunxiu; Goroff, Nancy S. Journal of the American Chemical Society, 2000 , vol. 122, # 38 p. 9320 - 9321
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Citation Number: 69
Abstract
Baeyer first reported the synthesis of diiodoacetylene (1) and diiodobutadiyne (2) in 1885. 1 Heilbronner and co-workers reported the synthesis of 2 in pure form in the 1970s. 2 These two molecules (Figure 1) have received renewed interest recently as precursors to conjugated polymers, including carbyne, 3 and as constituents in multicomponent conducting salts. 4 In the 115 years since Baeyer's initial description of 1 and 2, however, ...
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