Synthesis and reactivity of benzoxa (thia) zol-2-thiones: new route to 2-alkylthiobenzoxa (thia) zoles
A Harizi, A Romdhane, Z Mighri
Index: Harizi, Abdallah; Romdhane, Anis; Mighri, Zine Tetrahedron Letters, 2000 , vol. 41, # 31 p. 5833 - 5835
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Citation Number: 24
Abstract
The reaction of aromatic primary amines 1 with carbon disulfide in the presence of a catalytic amount of triethylamine followed by treatment with aqueous hydrogen peroxide leads to the corresponding benzoxa (thia) zol-2-thiones 3a–c which can be transformed with iminoethers into 2-alkylthiobenzoxa (thia) zoles 5a–h in good yields (64–85%).
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