The highly chemoselective transfer hydrogenation of the carbon–carbon double bond of conjugated nitroalkenes by a rhodium complex
J Xiang, EX Sun, CX Lian, WC Yuan, J Zhu, Q Wang…
Index: Xiang, Jing; Sun, Er-Xiao; Lian, Chun-Xia; Yuan, Wei-Cheng; Zhu, Jin; Wang, Qiwei; Deng, Jingen Tetrahedron, 2012 , vol. 68, # 24 p. 4609 - 4620
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Citation Number: 12
Abstract
Chemoselective transfer hydrogenation of conjugated nitroalkenes catalyzed by [RhCl2Cp∗] 2–diamine complex (Cp∗= η5-C5Me5) using HCOOH/Et3N (5: 2)(TEAF) as a hydrogen source was realized. A variety of nitrostyrenes, β-methyl nitrostyrenes, and 3- ...
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