Versatile desilylative cross-coupling of silyl enol ethers and allylic silanes via oxovanadium-induced chemoselective one-electron oxidation
T Hirao, T Fujii, Y Ohshiro
Index: Hirao, Toshikazu; Fujii, Takashi; Ohshiro, Yoshiki Tetrahedron, 1994 , vol. 50, # 34 p. 10207 - 10214
Full Text: HTML
Citation Number: 28
Abstract
Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The chemoselective cross-coupling of silyl enol ethers and allylic silanes to γ,δ-unsaturated ketones is achieved by the oxovanadium (V)-induced oxidative desilylation of the more readily oxidizable organosilicon compounds. ... The title oxidative intermolecular carbon-carbon bond ...
Related Articles:
[Tsuji, Jiro; Minami, Ichiro; Shimizu, Isao Chemistry Letters, 1983 , p. 1325 - 1326]
[Tsuda, Tetsuo; Chujo, Yoshiki; Nishi, Sei-ichi; Tawara, Kunio; Saegusa, Takeo Journal of the American Chemical Society, 1980 , vol. 102, # 20 p. 6381 - 6384]
[Tsuda, Tetsuo; Chujo, Yoshiki; Nishi, Sei-ichi; Tawara, Kunio; Saegusa, Takeo Journal of the American Chemical Society, 1980 , vol. 102, # 20 p. 6381 - 6384]
[Cantor; Tarbell Journal of the American Chemical Society, 1964 , vol. 86, p. 2902,2907]
Convenient Radical. ALPHA.-Monoallylations of Carbonyl Compounds.
[Watanabe, Yoshihiko; Yoneda, Tetsuo; Okumura, Tatsuya; Ueno, Yoshio; Toru, Takeshi Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 10 p. 3030 - 3033]