The Journal of Physical Chemistry

Thermal Decomposition of CF2ClO2NO2

JQ Xiong, RW Carr

Index: Xiong, Judy Qiuju; Carr, Robert W. Journal of Physical Chemistry, 1994 , vol. 98, # 39 p. 9811 - 9822

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Citation Number: 7

Abstract

The temperature and pressure dependence of the thermal decomposition kinetics of CF2C102N02 in the presence of N2 diluent have been investigated over the temperature range 272-289 K and over the total pressure range 3-40 Torr by time-resolved mass spectrometry. The measurements were performed by directly monitoring the molecular ion CF202N02'(mlz= 128), a fragment of CF~ C102N02. The CFzC102N02 decay rates are ...