Understanding the mechanism of B12-dependent diol dehydratase: a synergistic retro-push-pull proposal
DM Smith, BT Golding, L Radom
Index: Anderson, Rosaleen J.; Ashwell, Susan; Dixon, Ruth M.; Golding, Bernard T. Journal of the Chemical Society, Chemical Communications, 1990 , # l p. 70 - 72
Full Text: HTML
Citation Number: 82
Abstract
Ab initio molecular orbital theory is used to investigate the coenzyme B12-dependent reactions catalyzed by diol dehydratase. The key step in such reactions is believed to be a 1, 2-hydroxyl migration, which occurs within free-radical intermediates. The barrier for this
Related Articles:
[Andersen, Rosaleen J.; Ashwell, Susan; Garnett, Ian; Golding, Bernard T. Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 24 p. 4488 - 4498]
[Andersen, Rosaleen J.; Ashwell, Susan; Garnett, Ian; Golding, Bernard T. Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 24 p. 4488 - 4498]
[Andersen, Rosaleen J.; Ashwell, Susan; Garnett, Ian; Golding, Bernard T. Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 24 p. 4488 - 4498]
[Andersen, Rosaleen J.; Ashwell, Susan; Garnett, Ian; Golding, Bernard T. Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 24 p. 4488 - 4498]
[Andersen, Rosaleen J.; Ashwell, Susan; Garnett, Ian; Golding, Bernard T. Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 24 p. 4488 - 4498]