Unsaturated fatty alcohol derivatives as a source of substituted allylzirconocene

N Chinkov, A Levin, I Marek

Index: Chinkov, Nicka; Levin, Anat; Marek, Ilan Angewandte Chemie - International Edition, 2006 , vol. 45, # 3 p. 465 - 468

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Citation Number: 23

Abstract

The development and use of allylic organometallic reagents has been an underlying theme of modern organic synthesis.[1] A plethora of methods currently exists for the preparation of diversely substituted allylic organometallic moieties 2 by the displacement of pre-prepared allyl reagents 1 (Scheme 1). The Z group can be a halogen (Cl, Br, I),[1e] chalcogen (O, S, Se, Te),[2] metalloid (Pb, Sn),[3] or hydrogen,[2a, 4] but also carbon (in particular tertiary ...